ENGLISH |
中国科研实验室
| 发表年度： | 2018 |
|---|---|
| 期： | 3 |
| 卷： | 5 |
| 页： | 442-446 |
| 摘要： | Brominated thiazoloisoindigo was synthesized for the first time from thiazoloisatin, which was obtained via an unprecedented nucleophilic cyclization strategy. Thiazoloisoindigo was shown to exhibit a deeper LUMO energy level than isoindigo and thienoisoindigo, which makes it a potential building block for n-type semiconductors. Moreover, brominated thiazoloisoindigo is sensitive toward nucleophilic attack, and its reaction with aniline resulted in an unexpectedly much more stable acceptor with a LUMO energy level as low as -3.82 eV. |
| 刊物名称： | ORGANIC CHEMISTRY FRONTIERS |
| 影响因子： | 5.076 |
